Laminated tablecloth fabric is all cotton with a light acrylic coating on the surface to make the tablecloth or placemat (also available coated) just "wipe clean". Laminated tablecloth can also be laundered in a machine without using detergent and without hot temp for water. line dry, no iron. if the fabric looks really wrinkly, iron on reverse side of cloth with a cool iron.
Coated is the same for Laminated tablecloth descriptions.
Napkins are never coated or laminated. Napkins are always the 100% cotton version of the table linen item.